I've read about fuel cell for years. They have been around for ages and are great for some applications, space shuttle for example. I'm not so sure they work for everything. All the different new technological solutions seem to have more questions than answers. In this case with gallium. how much gallium do you need in order to continuously produce enough hydrogen to generate say 1 KW? Is any gallium consumed in the process? You seem far more informed than I am. Do you have any idea if any fuel cell ideas are capable of producing the power a sub needs but small enough to fit in a sub? If so do you think they can be price competitive with say litium ion batteries
Well I am no expert on the subject but my high school chemistry knowledge suggest that Gallium acts as a catalyst in the Aluminum water reaction therefore no Gallium will be spent in the process.
6Al+6H2O → 6AlOH + 6H → 6AlO + 6H2
This is actually a normal chemical reaction except during normal reaction the process goes too fast creating a AlO skin around the Aluminum material stopping further chemical reaction to occur.
I believe the Gallium acts as a reaction slowing catalyst sitting between the water molecule and Aluminum in exchanging electrons which slows the chemical reaction process. Gallium prices is around $US317/kg so it's not a highly expensive material compared to Platinum which was the main obstacle in wider use of fuel cells.
One problem that may arise with this material is collecting/disposal of the spent AlO and Gallium remaining within the reaction chamber. The material can be recycled but will weigh about the same in a slurry form and will require to periodically stop the reaction for maintenance.
As for size of a fuel cell generator if you look into my previous post you can see find a link to a diagram of 250kW generator within the presentation. My guess-timation of the Soryu class going 10knts requires about 2MW with time I believe that is a doable goal with more advance in material to create a more fast chemical reaction to generate electricity.