The National Engineering Research Center for Wide Bandgap Semiconductors
published a research result titled "(001) β-Ga 2 O 3 epitaxial layer grown with in-situ pulsed Al atom assisted method by MOCVD" in the authoritative journal Journal of Materiomics under Elsevier. This research innovatively proposed the pulsed aluminum atom assisted growth technology, successfully breaking through the key technical bottleneck of gallium oxide epitaxial material preparation, and laying the foundation for the research and development of a new generation of high-power electronic devices.
As a representative of ultra-wide bandgap semiconductor materials, gallium oxide has important strategic value in the fields of ultra-high voltage power electronics and deep ultraviolet detection. However, when using metal organic chemical vapor deposition (MOCVD) technology to prepare (001) crystal plane β-Ga 2 O 3 epitaxial layers, there are difficulties such as high surface roughness and high interface defect density, which seriously restrict the performance and reliability of devices. How to achieve high-flatness and low-defect thin film epitaxial growth has become a global research focus in this field.

In response to the above challenges, the team of researchers innovatively proposed an in-situ pulsed aluminum atom-assisted growth method. By precisely controlling the timing and concentration of pulsed aluminum atoms, a triple action mechanism is achieved during the epitaxial growth process: directional nucleation, aluminum atoms can serve as preferential nucleation sites to optimize the lattice arrangement orientation; inhibition of side reactions, effectively inhibiting the generation and desorption of by-products, and reducing oxygen vacancy defects; interface reconstruction, promoting atomic diffusion, weakening random island nucleation, and significantly improving the interface quality between the epitaxial layer and the substrate.
Experimental data show that the surface roughness (RMS) of the epitaxial layer prepared by the new method is reduced by more than 50%, the full width at half maximum (FWHM) of the X-ray rocking curve is as low as 45.2 arc seconds, and the oxygen vacancy defect density is reduced by an order of magnitude. The research team also observed the phenomenon of epitaxial orientation rotation for the first time, and proposed a theoretical model for the correlation between the rotation angle and surface flatness, providing new ideas for the precise control of epitaxial growth of materials.