That would be a massive escalation and totally inapproprate, China still recognises the Ukraine's soverignty. I doubt even Russia would want that as it could set the pretext for NATO to do something similar. Again, Russia now has multiple units of heavy artillery stationed all over Ukraine, it can hit major cities with much more sustained firepower than any single plane or drone can manage.Speaking of hypothetical Chinese military aid to Russia. I think it is possible, for China to send an PLAAF task group, consisting of a fleet of (24) J16, a fleet of drones, plus the C4ISR platforms and equipment, and a shit ton of PGMs.
Since Russia did NOT yet officially declare this a war, Russia can conduct joint drills and trainings with this PLAAF task group for a few days, and let the PLAAF aircraft engage in large scale precision guided bombing of, say, Kharkov. Because the city center of Kharkov is literally only some 30 km away from Russia/Ukraine border. J-16 will only need to enter Ukrainian air space very briefly, or can even stay within Russian border and deploy the munitions.
This can be coordinated with a Russian ground offensive.
However, I don't see this as something very likely.
If you really wanted to help Russia and test out the PLAAF's new toys then you may as well just attack Taiwan now. Less air miles and is a place actually meaningful to China.