Chinese Engine Development

silkroute

New Member
Registered Member
Graphene Used to Make Graphene Copper Composite that's 500 Times Stronger.


This research & its implication on developing 100s of times stronger alloys for aircraft engines might be of some interest to my friends here.


Researchers at the Korean Advanced Institute of Science and Technology (KAIST) have created composite materials using graphene that are up to 500 times stronger than the raw, non-composite material. This is the first time that graphene has been successfully used to create strong composite materials — and due to the tiny amounts of graphene used (just 0.00004% by weight) this breakthrough could lead to much faster commercial adoption than pure graphene, which is still incredibly hard to produce in large quantities.

At this point, we shouldn’t be wholly surprised that graphene — which holds a huge number of superlative titles, including the strongest material known to man — can also be used to create strong composite materials. In this case, the KAIST researchers created a copper-graphene composite that has 500 times the tensile strength of copper (1.5 gigapascals), and a nickel-grapehene composite that has 180 times the tensile strength of nickel (4 gigapascals). This is still some way off graphene’s tensile strength of 130 GPa — which is about 200 times stronger than steel (600 MPa) — but it’s still very, very strong. At 1.5 GPa, copper-graphene is about 50% stronger than titanium, or about three times as strong as structural aluminium alloys.

A diagram illustrating how to make graphene-copper and graphene-nickel composites

To create these composites, the KAIST researchers use a process called CVD (chemical vapor deposition) to grow monolayers (one-atom-thick layers) of graphene. These monolayers are then deposited onto a thin film of metal (copper or nickel). Another layer of metal is then evaporated (a method of deposition) on top of the graphene. This process is repeated, until you have a sandwich consisting of a few layers of metal and graphene. Different metal thicknesses were tested (between 70nm and 300nm), and it was found that thinner layers result in much stronger composites. Because graphene is so thin, the amount used is absolutely tiny: Just 0.00004% of the metals by weight.

How graphene prevents slip planes in copper/nickel graphene composites

The reason these composites are so strong is that the graphene stops the metal atoms from slipping and dislocating under stress. In a solid metal, if a slip plane forms (due to stress), the atoms will readily slip apart, causing a fracture. The layers of graphene stop the metal atoms from sliding — the metal atoms cannot physically pass through the super-strong graphene — so no fractures can form (pictured above). It’s essentially the metallic equivalent of steel-reinforced concrete. In case you were wondering, this is also one of the primary reasons why metals are nearly always used in alloy form — because there’s a mix of different metal atoms with different atom sizes, it’s much harder for slip planes to form.

Graphene-copper and graphene-nickel tensile strengthMoving forward, the researchers will now need to find a way of mass-producing these graphene-based composites, preferably with a roll-to-roll or metal sintering process. These composites, due to their massive strength, could find myriad uses in the automotive and aerospace industries, or simply as a new tool for structural engineers and industrial design. Just the sheer fact that we now know that graphene can be used as a composite is massive news, too: If graphene can suddenly turn soft copper into a structural material, imagine what it might do for something like titanium or steel, or even commercial polymers like Kevlar.

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latenlazy

Brigadier
Graphene Used to Make Graphene Copper Composite that's 500 Times Stronger.


This research & its implication on developing 100s of times stronger alloys for aircraft engines might be of some interest to my friends here.


Researchers at the Korean Advanced Institute of Science and Technology (KAIST) have created composite materials using graphene that are up to 500 times stronger than the raw, non-composite material. This is the first time that graphene has been successfully used to create strong composite materials — and due to the tiny amounts of graphene used (just 0.00004% by weight) this breakthrough could lead to much faster commercial adoption than pure graphene, which is still incredibly hard to produce in large quantities.

At this point, we shouldn’t be wholly surprised that graphene — which holds a huge number of superlative titles, including the strongest material known to man — can also be used to create strong composite materials. In this case, the KAIST researchers created a copper-graphene composite that has 500 times the tensile strength of copper (1.5 gigapascals), and a nickel-grapehene composite that has 180 times the tensile strength of nickel (4 gigapascals). This is still some way off graphene’s tensile strength of 130 GPa — which is about 200 times stronger than steel (600 MPa) — but it’s still very, very strong. At 1.5 GPa, copper-graphene is about 50% stronger than titanium, or about three times as strong as structural aluminium alloys.

A diagram illustrating how to make graphene-copper and graphene-nickel composites

To create these composites, the KAIST researchers use a process called CVD (chemical vapor deposition) to grow monolayers (one-atom-thick layers) of graphene. These monolayers are then deposited onto a thin film of metal (copper or nickel). Another layer of metal is then evaporated (a method of deposition) on top of the graphene. This process is repeated, until you have a sandwich consisting of a few layers of metal and graphene. Different metal thicknesses were tested (between 70nm and 300nm), and it was found that thinner layers result in much stronger composites. Because graphene is so thin, the amount used is absolutely tiny: Just 0.00004% of the metals by weight.

How graphene prevents slip planes in copper/nickel graphene composites

The reason these composites are so strong is that the graphene stops the metal atoms from slipping and dislocating under stress. In a solid metal, if a slip plane forms (due to stress), the atoms will readily slip apart, causing a fracture. The layers of graphene stop the metal atoms from sliding — the metal atoms cannot physically pass through the super-strong graphene — so no fractures can form (pictured above). It’s essentially the metallic equivalent of steel-reinforced concrete. In case you were wondering, this is also one of the primary reasons why metals are nearly always used in alloy form — because there’s a mix of different metal atoms with different atom sizes, it’s much harder for slip planes to form.

Graphene-copper and graphene-nickel tensile strengthMoving forward, the researchers will now need to find a way of mass-producing these graphene-based composites, preferably with a roll-to-roll or metal sintering process. These composites, due to their massive strength, could find myriad uses in the automotive and aerospace industries, or simply as a new tool for structural engineers and industrial design. Just the sheer fact that we now know that graphene can be used as a composite is massive news, too: If graphene can suddenly turn soft copper into a structural material, imagine what it might do for something like titanium or steel, or even commercial polymers like Kevlar.

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The challenge with jet engines, particularly the turbine blades, is not strength, but heat tolerance.
 
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silkroute

New Member
Registered Member
The challenge with jet engines, particularly the turbine blades, is not strength, but heat tolerance.

Yes, you are right. But, we don't know how these Graphene alloys will behave at higher temperatures. Do these display better tolerance at higher temps when compared to what alloys are currently being used in jet engines is yet be seen.
 

thunderchief

Senior Member
Graphene has very large melting temperature , around 4900 K :
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Real problem in mechanical application of graphene is that graphene is basically 2D structure , layer of atoms , therefore it is very hard to form thick enough composite structure with multiple layers upon layers . Koreans created few layers , but what would be really needed is thousand upon thousands . Also potential problem is metal sandwiched between graphene layers . It's own melting temperature and properties may be significantly inferior to graphene , significantly reducing performance .
 

latenlazy

Brigadier
Yes, you are right. But, we don't know how these Graphene alloys will behave at higher temperatures. Do these display better tolerance at higher temps when compared to what alloys are currently being used in jet engines is yet be seen.
It's specifically about mechanical tolerance at very high heat, which is why so much attention is paid to single crystal metals. Given my limited knowledge of material sciences, I'm skeptical that graphene has the bonding properties necessary to create a grain-less alloy, especially through this particular method of metal strengthening. If it's simply a composite structure and not a single crystal, the differential melting problems thunderchief cites disqualifies it as a viable material for jet turbine blades.
 
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silkroute

New Member
Registered Member
Graphene manufacturing could be greatly simplified using computer controlled printing processes for layered generation of composite materials.

That could be a one hell of a solution to manufacture graphene alloys if possible.

And i think you are on to something here; check this out. Ref:
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