Two things: I’m questioning the “surprised” part and I‘m also questioning the effectiveness of the American first strike.
When China and the US have heighten tensions, I expect the PLAAF to keep a fleet of KJ-500 in air covering all coastal approaches, the PLAN to send out picket forces out to act as trip wires and all air defence units active (or ready to be turn on to replace destroyed units). I expect many of the Tomahawks and drones get identified and destroyed.
Strategic surprise is unlikely to be achieved by either side, however operational surprise -- in terms of the exact timing, vectors, platforms and munitions used -- could very much be attainable to some degree.
As for the PLA's ability to "cover all coastal approaches" -- absolutely, the PLA would have active AEW&C and naval units as pickets and so on and so forth.
The question is whether the US are able to synchronize an air-naval-missile offensive that is able to blow multiple holes in the PLA's defenses (using stealth fighters to engage PLA AEW&C, using submarines and strike fighters to engage PLAN surface combatants), on the same day if not virtually the same hour as the US conducting their first wave strikes.
That would substantially reducing their effectiveness in defending against the first wave strikes from the US, which by the latter half of this decade, would constitute much more than just Tomahawks, instead they would likely include:
-land and submarine launched LRHW hypersonic glide vehicle weapons, possibly with some type of hypersonic cruise missile as well (which could be air launched)
-a lot, a lot of stealthy JASSM LACMs (and LRASM AShMs), launched from long range bombers at standoff range
-substantial F-35s with their own strike capabilities (including potentially JSM stealthy strike cruise missiles)
-and yes, Tomahawks launched from surface ships and submarines
Heck, depending on what sort of picket forces for the PLA we are talking about, even having an un-molested picket force, could still result in significant success from a US first wave strike simply because PLA capabilities are not yet as extensive as they need to be.
In short, I think you may be somewhat underestimating the capabilities the PLA needs to comprehensively and robustly track US westpac activities during peacetime and high tension (pre-conflict).
Your thinking about having a picket force is on the right track, but the distances you are thinking of are too short.
Instead of a few hundred kilometers outside of Chinese airspace, it should be something more like 4000km outside of Chinese airspace. And instead of simply waiting to receive and defend against an attack from the enemy launching long range weapons, the goal should be to try and as rapidly destroy the enemy after they launch their weapons (or even before they launch their weapons) to begin with, across as many of their mobile sea based platforms and fixed land based locations as possible.
That would require at least a half dozen operational carrier battle groups with escorts, many dozens and dozens of SSNs with a large complement of land attack weapons, many dozens and dozens of long range stealthy ISR and AEW UAVs, extensive satellite ISR coverage, many dozens and dozens of long range stealth bombers... and of course a very substantial stealth fighter fleet (on the order of well over a thousand) supported by a large fleet of traditional manned AEW&C, tankers and EW of course, and UCAVs as well depending on how mature they are.
Oh, and many hundreds of land based intermediate/regional ranged strike weapons across a number of domains as well, including hypersonic glide vehicles, hypersonic cruise missiles, IRBM/AShBMs, long range subsonic stealthy and non-stealthy cruise missiles.
Simply having KJ-500s orbit on the edges of Chinese airspace with active land based IADS and a few picket naval groups in the first island chain, is essentially a fixed defense whereby you have no real ability to take the initiative, and your defensive pickets will simply be targeted and destroyed in detail.
As a last line of defense, such a picket is fairly reasonable.
However, against the calibre of foe that they are up against, if they are forced to rely only on that last line of defense then chances are they are already at a major disadvantage.