This brings back memories of me a few years ago trying to pin down exactly what defines a propfan, and then just giving up. One can't say even that all propfans are unducted, because the NK-93 *does* have a duct. Perhaps one definite statement one can make about the distinction between turboprops and propfans is this: So far, for all engines called "turboprops," the axis of rotation of the propeller is offset from the axis of rotation of the compressors/turbines of the gas generator, while for all engines called "propfans," the axis of rotation of the propeller/fan is the same as the axis of rotation of the compressors/turbines.
As for any clear distinction between propfans and turbofans, well.... For example, I've seen online statements that the NK-93 geared "propfan" has a bypass ratio in the range of 16-17, while the under-development Rolls-Royce UltraFan geared "turbofan" has a bypass ratio of 14-15, which to me isn't that far off. Plus, the UltraFan apparently has variable-pitch fan blades! So it seems to me there's a plausible case that the UltraFan is crossing over into "ducted propfan" territory.