This is actually an interesting question. I don't know, but I speculate no because there are too much to do and too few launch windows to waste on relay satellites.
Judging by China's approach to its Moon missions, Tianwen 1's backup will become Tianwen 2 and go to Mars. There's no place in the plan for extra orbiters unless China is willing to do a multi-launch mission.
A multi-launch mission would open up more possibilities. On a second rocket, China can send two Tianwen series satellites outfitted with different instruments, or a single much more capable mapping/relay satellite to Mars. Still, what new capabilities would that demonstrate? None that I could see. So, I hope they would go for something far more ambitious.
With one launcher carrying an orbiter, the payload of the other rocket could be devoted entirely to the lander. In fact, with that spare capacity, get rid of the rover entirely and put in an ascender. Instead of a pure orbiter, have an orbiter/return capsule combo. Such mission would definately require aerobraing and direct desecend from Mars Transfer Orbit. Aside from these, most of the technologies have already been demonstrated in a Moon mission.
So, worst case scenario is that they get to test some of the technologies required for a sample return mission. Best case scenario is... well, one can dream.