Quickie
Colonel
No, LM-5B core stage is separated from payload under spring power not retro-rocket. They talked about this during the live broadcast of the launch.
Either the people on the broadcast are wrong (which seems unlikely), or else if there are retro-rockets then it must be for deorbiting burn.
In regard to the retro-rocket, I was not referring to LM-5B but the Atlas V launcher in the video posted.